The thermal boundary layer is a fluid boundary layer that is measures the temperature of a fluid as it flows over a surface. The concentration boundary layer is essentially the same thing but it measures mass instead.
Heavily related to velocity boundary layer.

The thermal boundary layer thickness,
Heat flux given by the following:
Using this we can find an expression for the convection heat transfer coefficient. If
Then plugging this into our equation for heat flux we get:
See ME3304 S24 Lecture Note (3) Convection for more info.
Equation 6.14:
The derivation of Equation 6.14 is shown in 9A - 2nd Class.